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Single-phase body-centered cubic (bcc) refractory medium- or high-entropy alloys can retain compressive strength at elevated temperatures but suffer from extremely low tensile ductility and fracture toughness. We examined the strength and fracture toughness of a bcc refractory alloy, NbTaTiHf, from 77 to 1473 kelvin. This alloy’s behavior differed from that of comparable systems by having fracture toughness over 253 MPa·m^1/2, which we attribute to a dynamic competition between screw and edge dislocations in controlling the plasticity at a crack tip. Whereas the glide and intersection of screw and mixed dislocations promotes strain hardening controlling uniform deformation, the coordinated slip of <111> edge dislocations with {110} and {112} glide planes prolongs nonuniform strain through formation of kink bands. These bands suppress strain hardening by reorienting microscale bands of the crystal along directions of higher resolved shear stress and continually nucleate to accommodate localized strain and distribute damage away from a crack tip. 

Hybrid-electric aircraft represent an important step in the transition from conventional fuel-based propulsion to fully-electric aircraft. For hybrid power systems, overall aircraft performance and efficiency highly depend on the coordination of the fuel and electrical systems and the ability to effectively control state and input trajectories at the limits of safe operation. In such a safety-critical application, the chosen control strategy must ensure the closed-loop system adheres to these operational limits. While hierarchical Model Predictive Control (MPC) has proven to be a computationally efficient approach to coordinated control of complex systems across multiple timescales, most formulations are not supported by theoretical guarantees of actuator and state constraint satisfaction. To provide guaranteed constraint satisfaction, this paper presents set-based hierarchical MPC of a 16 state hybrid-electric aircraft power system. Within the proposed two-level vertical hierarchy, the long-term control decisions of the upper-level controller and the short-term control decisions of the lower-level controller are coordinated through the use of waysets. Simulation results show the benefits of this coordination in the context of hybrid-electric aircraft performance and demonstrate the practicality of applying set-based hierarchical MPC to complex multi-timescale systems. 

Abstract We report on the largest open‐shell graphenic bilayer and also the first example of triply negatively charged radical π‐dimer. Upon three‐electron reduction, bilayer nanographene fragment molecule (C₉₆H₂₄Ar₆)₂(Ar=2,6‐dimethylphenyl) (1₂) was transformed to a triply negatively charged species1₂^3.−, which has been characterized by single‐crystal X‐ray diffraction, electron paramagnetic resonance (EPR) spectroscopy and magnetic properties on a superconducting quantum interference device (SQUID).1₂^3.−features a 96‐center‐3‐electron (96c/3e) pancake bond with a doublet ground state, which can be thermally excited to a quartet state. It consists of 34 π‐fused rings with 96 conjugatedsp²carbon atoms. Spin frustration is observed with the frustration parameterf>31.8 at low temperatures in1₂^3.−, which indicates graphene upon reduction doping may behave as a quantum spin liquid.